Network
formation and curvature driven flow of structured interfaces
Keith Promislow,
Michigan State
University
Abstract:
We present a novel interfacial
energy which unfolds the Canham-Helfrich energy. Combining elementary
differential geometry with dynamical systems techniques, we
construct critical points by balancing structural energy against
negative surface area terms. In R^3 we show that a universal unfolding
leads to formation of bilayer, radial pore, and spherical micellular
(pearled pore) networks. We derive a thin-interface limit of bilayer
structures we reduces an associated gradient flow to a
Kuramoto-Sivashinsky type curvature driven flow coupled to the
interfacial structure. We present applications to pore formation
and ion conduction in polymer electrolytes, in particular a fitting of
SAXS data, and discuss the use of Temperature Accelearted MD to
calibrate the models to subscale simulations.